000			01762nab a2200229 4500
005			20260520003110.0
008			260224s2015 xxu ing
041			_aInglés
245	0	0	_aEffect of Post-Synthesis Treatments on the Properties of ZnS Nanoparticles _bAn Experimental and Computational Study
260			_a _b _csept./oct. 2015
270			_a18/01/2016 ; 18/01/2016
300			_a12 p. ; 817-829
520			_aTranscripción del resumen del autor: This work deals with the characterization of ZnS NanoParticles (NP), prepared by precipitation employing thioacetamide as sulfur source at different reaction time length. The attention is focused on the modification induced on structural, surface and electronic properties of ZnS NP by post-synthesis treatments. These were aimed at removing from the samples surface adsorbed reactants, by washing or thermal treatments, both in air or vacuum. The effect of these parameters is followed by X-Ray Diffraction (XRD), Transmission Electron Microscopy (TEM), Fourier Transform InfraRed (FTIR), gas-volumetric and ThermoGravimetric Analysis (TGA). Moreover, the effect of nanostructuration on the semiconducting material band gap is evaluated by Diffuse Reflectance UV-Vis (DR UV-Vis) spectroscopy. Density Functional Theory (DFT) calculations have been employed to clarify the role of the adsorbed reactants on the surface stability and to assess the relationship between particle size and band gap value.
581			_a5
773	0		_tOil and Gas Science and Technology _g70
942			_cARTICULO
100	1		_aBalantseva, Elena _955081
100	1		_aCamino, Bruno _955082
100	1		_aFerrari, Anna Maria _955083
100	1		_aBerlier, Gloria _955084
999			_c189425 _d189425