000			02407nab a2200229 4500
005			20260520000316.0
008			260224s2013 xxu ing
041			_aInglés
245	0	0	_aPorosity of Devonian and Mississippian New Albany Shale across a maturation gradient _bInsights from organic petrology, gas adsorption, and mercury intrusion
260			_a _b _coct. 2013
270			_a10/12/2013 ; 10/12/2013
300			_a22 p. ; 1621-1643
520			_aTranscripción del resumen del autor: The evolution of porosity in shales with increasing maturity was examined in a suite of five New Albany Shale samples spanning a maturity range from immature (vitrinite reflectance, Ro 0.35%) to postmature (Ro 1.41%). Devonian to lower Mississippian New Albany Shale samples from the Illinois Basin used in this study contain marine type II kerogen having total organic carbon contents from 1.2 to 13.0 wt. %. Organic petrology, CO2 and N2 low-pressure adsorption, and mercury intrusion capillary pressure techniques were used to quantify pore volumes, pore sizes, and pore-size distributions. Increasing maturity of the New Albany Shale is paralleled by many changes in the characteristics of porosity. The total porosity of 9.1 vol. % in immature New Albany Shale decreases to 1.5 vol. % in the late mature sample, whereas total pore volumes decrease from 0.0365 to 0.0059 cm3/g in the same sequence. Reversing the trend at even higher maturity, the postmature New Albany Shale exhibits higher porosity and larger total pore volumes compared to the late mature sample. With increasing maturity, changes in total porosity and total pore volumes are accompanied by changes in pore-size distributions and relative proportions of micropores, mesopores, and macropores. Porosity-related variances are directly related to differences in the amount and character of the organic matter and mineralogical composition, but maturity exerts the dominant control upon these characteristics. We conclude that organic matter transformation due to hydrocarbon generation and migration is a pivotal cause of the observed porosity differences.
581			_a10
773	0		_tAAPG Bulletin _g97
942			_cARTICULO
100	1		_aMastalerz, Maria _944042
100	1		_aSchimmelmann, Arndt _944043
100	1		_aDrobniak, Agnieszka _944044
100	1		_aChen, Yanyan _953665
999			_c188038 _d188038