000 01889nab a2200253 4500
005 20260520003103.0
008 260224s2012 xxu ing
041 _aInglés
245 0 0 _aThermodynamic Properties of 1:1 Salt Aqueous Solutions with the Electrolattice Equation of State
260 _a
_b
_csept./oct. 2012
270 _a08/08/2013 ; 08/08/2013
300 _a15 p. ; 255-270
520 _aTraducción del resúmen del autor: The electrolattice Equation of State (EOS) is a model that extends the MattediTavares-Castier EOS (MTC EOS) to systems with electrolytes. This model considers the effect of three terms. The first one is based on a lattice-hole model that considers local composition effects derived in the context of the generalized Van der Waals theory: the MTC EOS was chosen for this term. The second and the third terms are the Born and the MSA contributions, which take into account ion charging and discharging and long-range ionic interactions, respectively. Depending only on two energy interaction parameters, the model represents satisfactorily the vapor pressure and the mean ionic activity coefficient data of single aqueous solutions containing LiCI, LiBr, LiI, NaCl, NaBr, NaI, KCl, KBr, KI, CsCl, CsBr, CsI, or RbCI. Two methods are presented and contrasted: the salt-specific and the ion-specific approaches. Therefore, the aim of this work is to calculate thermodynamic properties that are extensively used to design, operate and optimize many industrial processes, including water desalination.
581 _a2
773 0 _tOil and Gas Science and Technology
_g68
942 _cARTICULO
100 1 _aZuber, A.
_953411
100 1 _aCheconi, R.F.
_953412
100 1 _aMathew, R.
_953413
100 1 _aSantos, J.P.L.
_953414
100 1 _aTavares, F.W.
_953415
100 1 _aCastier, M.
_953416
999 _c187842
_d187842