000			02047nab a2200229 4500
005			20260520003059.0
008			260224s2012 xxu ing
041			_aInglés
245	0	0	_aMechanical Degradation Onset of Polyethylene Oxide Used as a Hydrosoluble Model Polymer for Enhanced Oil Recovery
260			_a _b _cnov./dic. 2012
270			_a03/05/2013 ; 03/05/2013
300			_a9 p. ; 931-940
520			_aTraducción del resúmen del autor: Water soluble polymers such as polyacrylamide are used in polymer flooding, which is an advanced technique of Enhanced Oil Recovery (EOR). It aims at improving crude oil displacement in reservoir by pushing it with a viscous injected fluid. Polymer flood is challenged by mechanical degradation of long macromolecules during intense flows. Many studies reported that above a critical extensional rate , polymer chains can break and lose their rheological properties. The molecular weight (M) dependence of for dilute solutions in laminar flows was shown to follow a power law: ˜ Mw–k. An experimental study has been performed to investigate the onset of mechanical degradation in both laminar and turbulent flows and for both dilute and semi dilute polyethylene oxide aqueous solutions. It reveals that the exponent k strongly depends on the concentration and flow regimes and also on solvent quality. Results show that mechanical degradation mainly affects long chains, that it is favoured at high concentrations, under poor solvent conditions. They also evidence that the extensional viscosity at low strain rates decreases to the same extent as shear viscosities due to mechanical degradation. However, the decrease of the extensional viscous properties at high strain rates is much more pronounced.
581			_a6
773	0		_tOil and Gas Science and Technology _g67
942			_cARTICULO
100	1		_aDupas, A. _953093
100	1		_aHénaut, I. _934825
100	1		_aArgillier, J.F. _916524
100	1		_aAubry, T. _953094
999			_c187652 _d187652