000 01840nab a2200217 4500
005 20260520001103.0
008 260224s2012 xxu
245 0 0 _aUse of aqueous solutions to simulate supercritical CO2 corrosion
260 _a
_b
_cabr. 2012
270 _a04/05/2012 ; 04/05/2012
300 _a10 p. ; 045004-1 / 045004-11
520 _aTranscripción del resumen del autor: Capturing and storage of anthropogenic carbon dioxide (CO2) requires the transport of CO2 with varying combinations of impurities depending on the capture technology and source. Traditional pipelines are not designed for the transport of such relatively low-purity CO2; in fact, initial research indicates that a low-purity CO2 environment poses a significant durability risk to conventional (gas) pipelines. The presence of water in a supercritical CO2 stream will lead to acidic conditions via the formation of carbonic acid (H2CO3). In this work, a round robin of experiments has been executed in aqueous solutions where CO2 has been added to water to form H2CO3 in situ, along with testing in sulfuric acid (H2SO4) that was found to simulate the impact of H2CO3 upon steel. The role of Cl-, NO3-, and SO42- impurities was also investigated. Conclusions have been drawn from electrochemical, weight-loss, and optical profilometry results, with future work outlined. While not a replacement to supercritical CO2 experiments, we see that there is significant merit in such high throughput tests to form an initial understanding, which can be subsequently benchmarked by supercritical CO2 tests.
581 _a4
773 0 _tCorrosion
_g68
942 _cARTICULO
100 1 _aSim, S.
_952531
100 1 _aCorrigan, P.
_952532
100 1 _aCole, I.S.
_952533
100 1 _aBirbilis, N.
_944824
999 _c187134
_d187134