000 01441nab a2200205 4500
005 20260520001042.0
008 260224s2011 xxu
245 0 0 _aRole of chloride, sulfate, and alkalinity on galvanic lead corrosion
260 _a
_b
_cjun. 2011
270 _a27/06/2011 ; 27/06/2011
300 _a9 p. ; 065005
520 _aTranscripción del resumen del autor. Effects of chloride, sulfate, and alkalinity on galvanic corrosion were investigated using beaker tests, lead wire electrochemical tests, and lead solder galvanic cells. At relatively high concentrations of lead and low pH values that might be present at the lead anode surface, sulfate forms precipitates with lead while chloride forms soluble complexes, explaining the detriments of chloride and benefits of sulfate during galvanic corrosion in prior research. Considering these factors and transport equations for anions in water, a chloride-to-sulfate mass ratio (CSMR) above 0.77 is predicted to concentrate more chloride than sulfate at the lead anode surface, whereas the converse occurs below this level of CSMR. Bicarbonate can compete with chloride and sulfate transport and buffer pH at the anode surface, providing benefits to lead corrosion.
581 _a6
773 0 _tCorrosion
_g67
942 _cARTICULO
100 1 _aNguyen, C.K.
_950500
100 1 _aClark, B.N.
_950501
100 1 _aStone, K.R.
_950502
999 _c183189
_d183189