000 01669nab a2200205 4500
005 20260520001028.0
008 260224s2011 xxu
245 0 0 _aInfluence of alloying elements Ga and Hg on electrochemical corrosion behavior of Mg solid solution
260 _a
_b
_cmayo 2011
270 _a19/05/2011 ; 19/05/2011
300 _a6 p. ; 055003
520 _aTranscripción del resumen del autor. The electrochemical corrosion behavior of Mg1.5Ga, Mg3Ga, and Mg1.5Hg1.5Ga (at%) alloys with an a-Mg single phase were investigated by potentiodynamic and galvanostatic testing. The corroded surface morphologies of Mg alloys were observed using scanning electron microscopy (SEM), and its corrosion products were determined using x-ray diffraction analysis (XRD) and energy spectrum analysis (ESA). The results show that the solid solution of Ga and Hg in a-Mg promotes the electrochemical activity of Mg alloys, and the influence of Hg is greater than that of Ga. It is ascribed to the formation of Mg amalgams, namely, HgMg and Ga5Mg2, which react with water and promote the dissolution and discharge of a-Mg. The most negative stable potential of -1.80 V and open-circuit potential of -1.94 V occurs in the Mg1.5Hg1.5Ga alloy. The addition of 1.5 at% Ga to Mg1 .5Ga alloy increases the corrosion current density from 1.410 mA/cm2 to 1.794 mA/cm2, while the addition of 1.5 at% Hg increases the corrosion current density from 1.794 mA/cm2 to 5.282 mA/cm2.
581 _a5
773 0 _tCorrosion
_g67
942 _cARTICULO
100 1 _aFeng, Y.
_926047
100 1 _aWang, R.C.
_949896
100 1 _aPeng, C.Q.
_949897
999 _c181827
_d181827