000 01651nab a2200205 4500
005 20260522181321.0
008 260224s2010 xxu
100 1 _aAmri, J.
_945779
100 1 _aGulbrandsen, E.
_940148
100 1 _aNogueira, R.P.
_945780
245 0 0 _aPropagation and Arrest of Localized Attacks in Carbon Dioxide Corrosion of Carbon Steel in the Presence of Acetic Acid
260 _cmar. 2010
270 _a20/07/2010 ; 20/07/2010
300 _a7 p. ; 035001
520 _aTranscripción del resumen del autor. The presence of acetic acid (HAc) has been identified as one factor that may contribute to enhance localized top-of-the-line corrosion attacks in gas condensate pipelines. The role of free HAc on the growth of localized attacks in carbon dioxide (CO2) corrosion of carbon steel pipelines therefore was studied by means of a preinitiated localized attack electrode assembly ("artificial pit electrode"). The current flowing between the localized attack and the outer surface was measured with a zero-resistance ammeter. It is shown that the corrosion potential increases with increasing free HAc concentration. Depletion of free HAc inside the attack imposed a potential difference that triggered the propagation of the attack at room temperature. The pit growth was self-sustained in CO2 and HAc environments only to a certain depth, beyond which the dissolution current at the bottom of the attack vanished. This is in good agreement with field observations in the case of top-of-the-line corrosion phenomena.
581 _a3
773 0 _tCorrosion
_g66
942 _cARTICULO
_2ddc
999 _c175115
_d175115