000 01633nab a2200205 4500
005 20260520000928.0
008 260224s2011 xxu
245 0 0 _aApplication of an fourier transform-infrared imaging tool for measuring temperature or reaction profiles in pyrolyzed wood
260 _a
_b
_cene./feb. 2011
270 _a04/04/2011 ; 04/04/2011
300 _a9 p. ; 370–378
520 _aTranscripción del resumen del autor. FT-IR imaging was used to monitor the structural and chemical changes of wood particles under various pyrolysis conditions. The temperature or reaction profile inside pyrolyzed wood was obtained from a novel approach using chemical images coupled with multivariate analysis. Poplar sections 100 µm thick were pyrolyzed at 250-500 °C and the resulting FT-IR images were used as standards to determine the temperature in a poplar wood block (5 mm × 5 mm × 20 mm). Principal component analysis (PCA) and partial least-squares (PLS) regression were used to develop predictive models to map the temperature profile in the pyrolyzed wood. The results indicate that FT-IR imaging coupled with multivariate analysis is a powerful tool to study the heat transfer effects in the pyrolysis of thick wood particles. We believe that this is a unique and novel approach to visualize the chemical changes in heated biomass and thermal effects in other materials.
581 _a1
773 0 _tEnergy & fuels
_g25
942 _cARTICULO
100 1 _aBahng, Mi-Kyung
_945072
100 1 _aDonohoe, Bryon s.
_942719
100 1 _aNimlos, Mark R.
_942718
999 _c174415
_d174415