000			01888nab a2200193 4500
005			20260520000227.0
008			260224s2010 xxu
245	0	0	_aGeochemical characterization of gases from the Mississippian Barnett Shale, Fort Worth Basin, Texas
260			_a _b _cnov. 2010
270			_a20/12/2010 ; 20/12/2010
300			_a16 p. ; 1641-1656
520			_aTranscripción del resumen del autor. Molecular and isotopic compositions of 51 gas and 7 condensate samples produced from the Barnett Shale were determined by gas chromatography–isotope ratio mass spectrometry to investigate their origin and maturity at the time of generation. Additionally, two hydrous pyrolysis experiments were performed to calibrate maturity values predicted for gas generation. Molecular and carbon and hydrogen isotopic compositions of the gases indicate that gas produced from the Barnett is thermogenic. To estimate generation maturity, additional analyses were performed on the condensates and available core samples. Diamondoid indices combined with vitrinite reflectance (Ro) measurements, isotopic and molecular composition, and hydrous pyrolysis experiments suggest that gas produced from the Barnett Shale was generated within the condensate–wet gas window (1.3–2.0% Ro) at a later stage than hydrocarbons accumulated in shallower reservoirs. The origin of the gas is thermogenic, probably derived from both kerogen cracking and secondary cracking of previously generated nonmigrated hydrocarbons. Additionally, the occurrence of a methane isotope reversal in group 1 gases corroborates that in-situ oil or gas cracking is occurring in the easternmost part of the study area.
581			_a11
773	0		_tAAPG Bulletin _g94
942			_cARTICULO
100	1		_aRodriguez, Norelis D. _944037
100	1		_aPhilp, Paul P. _944038
999			_c172379 _d172379