000 01623nab a2200205 4500
005 20260520000856.0
008 260224s2009 xxu
245 0 0 _aElectrochemical Behavior of Sn-Ag Alloys in Alkaline Solutions
260 _a
_b
_csep. 2009
270 _a07/07/2010 ; 06/07/2010
300 _a8 p. ; 587-594
520 _aTranscripción del resumen del autor. The behavior of four Sn-Ag alloys and their individual metal components in sodium hydroxide (NaOH) solutions was studied using open-circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). The results reveal that each of the initial open-circuit potential at zero time, Ei, and final open-circuit potential after 60 min, Ef, (at concentrations <0.30 M) shifts toward more negative values, indicating a relatively higher rate of dissolution during the spontaneous oxide growth/oxide dissolution process under the currentless conditions. While at concentrations <0.30 M, there is no significant change in potential. The two corrosion parameters (corrosion potential [Ecorr] and corrosion current density [icorr]) show a linear relation with both the solution concentration and alloy composition. EIS results show that each of the total resistance (RT) and reciprocal capacitance (C-1) values decreases with an increase in the tin content up to 50%. After that, there is little change in their values.
581 _a9
773 0 _tCorrosion
_g65
942 _cARTICULO
100 1 _aAmeer, M.A.
_943515
100 1 _aFekry, A.M.
_943516
100 1 _aGhoniem, A.A.
_943517
999 _c171810
_d171810