000 01876nab a2200205 4500
005 20260520000856.0
008 260224s2009 xxu
245 0 0 _aEffect of ethanol chemistry on stress corrosion cracking of carbon steel in fuel-grade ethanol
260 _a
_b
_cdic. 2009
270 _a07/07/2010 ; 06/07/2010
300 _a13 p. ; 785-797
520 _aTranscripción del resumen del autor. A systematic study was carried out to understand the effect of ethanol chemistry (chloride, water, pHe, and oxygen level) as well as other controlling parameters on the stress corrosion cracking (SCC) behavior of X-65 carbon steel in simulated fuel-grade ethanol (SFGE). The SCC susceptibility of carbon steel was evaluated using the slow strain rate testing (SSRT) method. Chlorides strongly affect the SCC initiation and growth, and a higher concentration of chloride leads to a higher crack density and velocity. The addition of water in the ethanol influences the surface passivation in SFGE. SCC-to-pitting corrosion transition was observed above 2.5% water concentration in SFGE. pHe was also found to be a critical factor influencing the SCC susceptibility with alkaline SFGE inhibiting SCC initiation in carbon steel. Strain rate affected the SCC behavior of carbon steel, where slower strain rate caused a larger crack length and a higher crack density, but a lower crack velocity. Hard inclusions (alumina and silicate) in X-65 steel acted as early crack initiation sites due to the higher local plastic deformation that occurred near the inclusions. By adjusting the ethanol chemistry, SCC susceptibility of a commercial fuel-grade ethanol can be mitigated.
581 _a12
773 0 _tCorrosion
_g65
942 _cARTICULO
100 1 _aLou, X.
_943507
100 1 _aYang, D.
_921331
100 1 _aSingh, P.M.
_934173
999 _c171803
_d171803