000 01323nab a2200205 4500
005 20260520000846.0
008 260224s2009 xxu
245 0 0 _aLiquid-phase cracking of dicyclopentadiene by reactive distillation
260 _a
_b
_cjul./ago. 2009
270 _a16/06/2010 ; 16/06/2010
300 _a5 p. ; 4077-4081
520 _aTranscripción del resumen del autor. A reactive distillation process was developed for cracking dicyclopentadiene (DCPD) to produce cyclopentadiene (CPD). In the autoclave reactor, reaction temperature, reaction time, diluent, and inhibitors are investigated to study the effect of inhibiting oligomerization reactions. The introduction of auxiliary diluent and inhibitors prevents the oligomerization reactions. On the basis of autoclave results, the reaction is studied on a reactive distillation apparatus to enforce the cracking of DCPD and prohibit oligomerization simultaneously. Hence, the yield and purity of CPD reach 90 and 98 wt %, respectively. Reactive distillation greatly alleviates the formation of oligomers compared with conventional processes.
581 _a4
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aCai, Zhi
_942793
100 1 _aShen, Benxian
_942794
100 1 _aLiu, Weilian
_942795
999 _c171086
_d171086