000 01747nab a2200205 4500
005 20260520001753.0
008 260224s2009 xxu
245 0 0 _aSeparating group compositions in naphtha by adsorption and solvent extraction to improve olefin yields of steam cracking process
260 _a
_b
_cjun. 2009
270 _a14/06/2010 ; 10/06/2010
300 _a5 p. ; 156-160
520 _aTranscripción del resumen del autor. In order to improve the steam cracking feeds, several model compounds including normal paraffins, isoparaffins, cyclanes and aromatics were selected as the feeds of steam cracking process and the olefin yields were investigated. In the typical reaction conditions, the normal paraffins in the naphtha contribute most to the ethylene in the products; the iso-paraffins are the main sources of the propylene; the cyclanes mainly produce the butadiene and the aromatics can hardly produce olefins. According to this, the adsorption process and solvent extraction process were adopted to separate the group compositions in naphtha properly to optimize the cracking feeds. The n-paraffins in naphtha were gathered through adsorption process using 5A molecular sieves. The ethylene yield improved by 13% using the desorption oil rich in n-paraffins as the cracking feed. The aromatics and the cyclanes were extracted from the naphtha. Compared with the naphtha, the ethylene and propylene yields of the extraction raffinate oil were 3.0 and 1.5% higher respectively.
581 _a3-4
773 0 _tJournal of Petroleum Science & Engineering
_g66
942 _cARTICULO
100 1 _aLiu, Ji-Chang
_941652
100 1 _aShen, Ben-Xian
_941653
100 1 _aWang, Da-qi
_942532
999 _c170917
_d170917