000 01539nab a2200205 4500
005 20260520000839.0
008 260224s2009 xxu
245 0 0 _aCharacterization of thermally pretreated kukersite oil shale using the solvent-swelling technique
260 _a
_b
_cnov./dic. 2009
270 _a09/06/2010 ; 09/06/2010
300 _a16 p. ; 5972-5977
520 _aTranscripción del resumen del autor. Equilibrium swelling of thermally pretreated kukersite oil shale has been investigated in 22 solvents and in 2 different binary mixtures to evaluate changes in the swelling behavior and solubility parameter. Swelling experiments were performed at room temperature on previously preheated samples. Variations in extent of solvent swelling as a function of the pretreatment temperature and time are shown. On the basis of swelling in high donor number solvents, kukersite oil shale shows structural relaxation before the onset of active pyrolysis. This is consistent with the behavior seen in coal pyrolysis studies on high tar yield, softening coals. The solubility parameters (Hildebrand and Hansen three-dimensional) of kerogen were tentatively determined from swelling data and found to be practically independent of the thermal pretreatment process conditions in the temperature range up to 350 °C.
581 _a6
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aSavest, Natalja
_942389
100 1 _aHruljova, Jelena
_942390
100 1 _aOja, Vahur
_942391
999 _c170841
_d170841