000 01517nab a2200205 4500
005 20260520000838.0
008 260224s2009 xxu
245 0 0 _aAnalysis on leaching characteristics of iron in coal fly ash under ammonia-based wet flue gas desulfurization (WFGD) conditions
260 _a
_b
_cnov./dic. 2009
270 _a09/06/2010 ; 09/06/2010
300 _a4 p. ; 5916-5919
520 _aTranscripción del resumen del autor. Iron leaching from fly ash has been investigated under simulated ammonia-based wet flue gas desulfurization conditions to determine the effects of the reaction temperature, initial pH value, liquid/solid ratio, and vibration frequency. The experimental results indicated that the ferric ion concentration in solution increased with the increase of the temperature and vibration frequency and the decrease of the pH value and liquid/solid ratio. The kinetics of iron leaching can be expressed as diffusion combined with a surface chemical reaction model. The reaction path can be described by the equation: 1 - (1 - a)1/3 = kt. The apparent activation energy was estimated to be about 20.01 kJ/mol. Such a value of the activation energy indicates that the leaching of iron under experimental conditions is controlled by both chemical reaction and diffusion.
581 _a6
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aGao, Xiang
_942369
100 1 _aDing, Hong-lei
_942370
100 1 _aWu, Zu-liang
_942371
999 _c170833
_d170833