000 01421nab a2200205 4500
005 20260520000836.0
008 260224s2009 xxu
245 0 0 _aCharacteristics of natural gas hydrates occurring in pore-spaces of marine sediments collected from the eastern Nankai trough, off Japan
260 _a
_b
_cnov./dic. 2009
270 _a08/06/2010 ; 08/06/2010
300 _a6 p. ; 5580-5586
520 _aTranscripción del resumen del autor. Pore-space gas hydrates sampled from the eastern Nankai Trough area off of Japan were minutely characterized using several instrumental techniques. Gas chromatographic results indicated that the natural gas in the sediment samples studied comprises mainly CH4. The concentrations of minor components varied according to depth. The powder X-ray diffraction patterns showed that the pore-space hydrates were of structure I (sI); the lattice constants were 1.183-1.207 nm. Both 13C NMR and Raman spectra confirmed that CH4 molecules were encaged in sI hydrate lattice. The average cage occupancies were calculated, respectively, from the Raman data as 0.83 for small cages and 0.97 for large cages. The hydration numbers were determined as 6.1-6.2.
581 _a6
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aKida, Masato
_942290
100 1 _aSuzuki, Kiyofumi
_942291
100 1 _aKawamura, Taro
_942292
999 _c170794
_d170794