000 02149nab a2200205 4500
005 20260520000835.0
008 260224s2009 xxu
245 0 0 _aExperimental study of combustion characteristics of bituminous char derived under mild pyrolysis conditions
260 _a
_b
_cnov./dic. 2009
270 _a08/06/2010 ; 07/06/2010
300 _a8 p. ; 5322-5330
520 _aTranscripción del resumen del autor. The combustion characteristics of chars derived from a bituminous coal (Datung, also denoted as DT) at different pyrolysis temperatures were studied via simultaneous thermal analysis (STA). The chars were obtained at pyrolysis temperatures of 550, 650, 750, and 850 °C. The carbon structure of chars and the parent coal were characterized using X-ray diffraction. Pore structures of chars and parent coal were measured by nitrogen adsorption. Based on the thermogravimetric analysis results, the ignition behavior and reactivity of the chars and the parent coal, as well as those of Yangquan (YQ) anthracite, were compared. The ignition temperature (Ti) and weighted mean apparent activation energy (Em) were obtained and used to evaluate reactivity. The results show that the ignition type of the bituminous parent coal and chars derived at 550, 650, and 750 °C is predominately hetero-homogeneous, whereas that of char derived at 850 °C and the YQ anthracite is heterogeneous. Thermal deactivation was observed under the pyrolysis conditions in this work. The reactivity of all chars is lower than that of the parent coal but higher than that of Yangquan anthracite. Moreover, the char that was derived at 650 °C has the highest reactivity among all chars. Carbon structure ordering contributes more to the thermal deactivation at high temperatures than at low temperatures. Changes in pore structure and material composition affect the reactivity for chars derived from both low and high temperatures.
581 _a6
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aShen, Chunmei
_942215
100 1 _aLin, Weigang
_942216
100 1 _aWu, Shaohua
_942217
999 _c170760
_d170760