000			01664nab a2200181 4500
005			20260520000827.0
008			260224s2009 xxu
245	0	0	_aSelective oxidation of a hydrotreated light catalytic gas oil to produce low-emission diesel fuel
260			_a _b _cene. 2009
270			_a27/07/2009 ; 27/07/2009
300			_a5 p. ; 799-804
520			_aTranscripción del resúmen publicado por el autor: LCO (light catalytic gas oil) hydrotreating was performed on a laboratory-scale trickle bed reactor to obtain a 15 ppm sulfur fuel. The fuel was then selectively oxidized using a CuCr/IP(4-PVP) catalyst in air at different operating conditions on a laboratory-scale continuously stirred tank reactor. The oxygenated and polyoxygenated compounds formed were measured by a previously developed HPLC GC-MS technique, and acid content and fuel stability were measured using standard ASTM analytical procedures. Additionally, a simplified reaction model was developed to predict oxygen incorporation into the LCO, and the oxygenated fuel was tested in a diesel engine. The results show a decrease in emissions by low-sulfur diesel oxidation, as well as the benefits of having a high selectivity toward ketone formation when using a CuCr/IP(4-PVP) catalyst. The need to carefully control the depths of oxygen incorporation to preserve fuel stability was verified. A simplified kinetic model is proposed to predict oxygen incorporation in the fuel.
773	0		_tEnergy & fuels _g23
942			_cARTICULO
100	1		_aGaliasso Tailleur, Roberto _941596
100	1		_aCasanova Caris, Pedro _941597
999			_c170198 _d170198