000 01509nab a2200205 4500
005 20260520000819.0
008 260224s2009 xxu
245 0 0 _aPreparation of an industrial Ni-based catalyst and investigation on CH4/CO2 reforming to syngas
260 _a
_b
_cfeb. 2009
270 _a15/05/2009 ; 29/04/2009
300 _a5 p. ; 607-612
520 _aTranscripción del resúmen publicado por el autor: An industrial cylinder Ni-based catalyst, LaNiOx/ZSM-5 ( = 3 mm), was prepared by a sol-gel method, and its catalytic performance was investigated for CH4/CO2 reforming reaction not only in laboratory scale but also in pilot plant scale. The result revealed that the conversion of CH4 and CO2 was 97% and 94%, respectively, at 850 °C and gas hour space velocity = 1.3 × 103 h-1 and remained a constant in the 100 h range, whereas carbon yield was ca. 5%. The properties of the catalyst were characterized by means of techniques such as X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) surface area, high-resolution transmission electron microscopy (HRTEM), temperature-programmed reduction (TPR), and temperature-programmed oxidation (TPO) and compared to those of La2NiO4/MCM-41 and La2NiO4/ -Al2O3 catalysts.
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aTian, L.
_941052
100 1 _aZhao, X.H.
_941053
100 1 _aLiu, B.S.
_941054
999 _c169665
_d169665
856 _uhttp://pubs.acs.org/doi/full/10.1021/ef800647n