000 01666nab a2200205 4500
005 20260520000817.0
008 260224s2009 xxu
245 0 0 _aPreparation, structural characterization, and activity for ethanol oxidation of carbon-supported PtSnIn catalyst
260 _a
_b
_cene. 2009
270 _a15/05/2009 ; 17/04/2009
300 _a4 p. ; 403-407
520 _aTranscripción del resúmen publicado por el autor: Carbon-supported ternary PtSnIn (atomic ratios of 60:20:20, 60:30:10, and 60:10:30) catalysts were prepared using NaBH4 as a reducing agent in ethylene glycol solution. The obtained catalyst was characterized by inductively coupled plasma-atomic emission spectrometry (ICP-AES), transmission electron microscopy (TEM), and X-ray diffraction (XRD) analyses in comparison to PtSn and PtIn catalysts prepared in the same way. The results showed that all of the catalysts displayed similar particle morphology, while the lattice parameter of PtSnIn was lower than that of PtIn and higher than that of PtSn. Linear sweep voltammetry measurements indicated that PtSnIn catalyst had an enhanced activity for ethanol oxidation compared to both PtSn and PtIn catalysts, consistent with the results of a single-cell test. It was suggested that the enhanced ethanol oxidation activity of PtSnIn catalyst was attributed to the formation of a ternary PtSnIn alloy.
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aZhu, Mingyuan
_940944
100 1 _aSun, Gongquan
_940945
100 1 _aYan, Shiyou
_940946
999 _c169598
_d169598
856 _uhttp://pubs.acs.org/doi/full/10.1021/ef800726b