000 01590nab a2200205 4500
005 20260520000816.0
008 260224s2009 xxu
245 0 0 _aPost-treatment of fly ash by ozone in a fixed bed reactor
260 _a
_b
_cene. 2009
270 _a15/05/2009 ; 15/04/2009
300 _a5 p. ; 280-285
520 _aTranscripción del resúmen publicado por el autor: The residual carbon in fly ash produced from pulverized coal combustion can adsorb the air-entraining admixtures (AEAs) added to enhance air entrainment in concrete. This behavior of the ash can be suppressed by exposing the fly ash to oxidizing species, which oxidizes the carbon surface and thus prevents the AEA to be adsorbed. In the present work, two fly ashes have been ozonated in a fixed bed reactor and the results showed that ozonation is a potential post-treatment method that can lower the AEA requirements of a fly ash up to 6 times. The kinetics of the carbon oxidation by ozone was found to be fast. A kinetic model has been formulated, describing the passivation of carbon, and it includes the stoichiometry of the ozone consumption (0.8 mol of O3/kg of C) and an ineffective ozone loss caused by catalytic decomposition. The simulated results correlated well with the experimental data.
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aPedersen, Kim Hougaard
_940893
100 1 _aCasanovas Meliá, Mercé
_940894
100 1 _aJensen, Anker Degn
_940895
999 _c169567
_d169567
856 _uhttp://pubs.acs.org/doi/full/10.1021/ef800532x