000 01599nab a2200193 4500
005 20260520000814.0
008 260224s2009 xxu
245 0 0 _aComparison of novozym 435 and amberlyst 15 as heterogeneous catalyst for production of biodiesel from palm fatty acid distillate
260 _a
_b
_cene. 2009
270 _a14/04/2009 ; 13/04/2009
300 _a3 p. ; 1-4
520 _aPalm fatty acid distillate (PFAD), a byproduct from the palm oil refinery process, has recently been utilized as an alternative feedstock for biodiesel (BD) production via homogeneous acid-catalyzed esterification. This process suffers from catalyst recovery, wastewater treatment, and BD purification. To minimize the problem, heterogeneous catalysts, Novozym 435 (immobilized Candida antarctica lipase B) and Amberlyst 15 (acidic styrene-divinylbenzene sulfonated ion-exchange resin), are tested and their catalytic activities under various reaction conditions are compared. Novozym 435 acts fast and its optimal specific activity (g BD/h/g catalyst) is 50-fold higher than that of Amberlyst 15. The maximum BD yields obtained using Novozym 435 and Amberlyst 15 are 95 and 97%, respectively. Both catalysts are recycled more than 15 cycles without losing their activities. The results suggest that both Novozym 435 and Amberlyst 15 can be effectively used for BD production from PFAD.
773 0 _tEnergy & fuels
_g23
942 _cARTICULO
100 1 _aRahman Talukder, M.M.
_940788
100 1 _aWu, J.C.
_940789
100 1 _aLau, S.K.
_940790
999 _c169511
_d169511