000 01660nab a2200205 4500
005 20260520000800.0
008 260224s2009 xxu
245 0 0 _aAnodic characteristics of copper, wrought CuNi 10, and CuA|10Ni5Fe4 in seawater
_bPart 1 - Polarizations below 200 mV at rotating disc electrodes and rotating cylinder electrodes
260 _a
_b
_cene. 2009
270 _a19/01/2009 ; 16/01/2009
300 _a12 p. ; 24-36
520 _aThe anodic, chloride ion-facilitated dissolution of copper, wrought 90-10 copper-nickel, and wrought nickel aluminum bronze, in controlled aqueous chloride electrolutes, has been examined at comparatively low values of polarization, i.e., <200 mV relative to the corrosion potential. Laminar flow to a rotating disc electrode (80 <Re rde < 3,800) and turbulent flow around a rotating cylinder electrode (1.920 <Re rce <26,100) were considered at low values of anodic polarization. Using diagnostic factors that were previously developed for unalloyed copper, the dissolution characteristics of the materials have been compared in a systematic manner. A kinetic model, in conjunction with convective-diffusion theory, has been applied to describe the general behavior of all three materials. The chloride ion facilitated a relatively rapid rate of dissolution via cruprous dichloride ion formation, and each system showed mixed (charge and mass transport) control of the anodic disolution.
581 _a1
773 0 _tCorrosion
_g65
942 _cARTICULO
100 1 _aKear, G.
_933062
100 1 _aBarker, B.D.
_933063
100 1 _aStokes, K.R.
_940172
999 _c168889
_d168889