TY  - SER
TI  - Dilute iota- and kappa-carrageenan solutions with high viscosities in high
PY  - 2011///
CY  - 
PB  - 
N2  - Transcripción del resumen del autor: We evaluated the rheological characteristics of - and -Carrageenan in aqueous solutions. Viscosities strongly increased with increasing polymer concentration or salinity. Monovalent Na+ cations were more effective in increasing viscosity than divalent Ca2+ cations. A more complex brine containing Na+, Mg2+ and Ca2+ cations also showed high viscosities at a high salinity. We observed shear thinning behavior for these polysaccharide solutions. We explain these rheological phenomena with molecular processes, specifically the conformation change of the -Carrageenan from random coil to double helix. In the context of enhanced oil recovery, -Carrageenan solutions can reach much higher viscosities at high salinities than standard polyacrylamide solutions. Moreover, Carrageenans are renewable, nontoxic, green substances
ER  -