01194nab a2200193 4500 20260520000814.0 260224s2009 xxu Benzylation of anisole catalyzed by MoCI5/molecular sieve system ene. 2009 14/04/2009 ; 14/04/2009 3 p. ; 51-54 Transcripción del resúmen publicado por el autor: MoCl5 was found as a new catalyst for the benzylation of anisole. In comparison to the general Lewis acid, such as FeCl3, ZnCl2, and AlCl3, the reactivity of MoCl5 was higher than AlCl3 but lower than FeCl3 under the same reaction conditions. When MoCl5 was supported on HZSM-5 or TS-1 molecular sieve, the yield of this reaction was increased from 45% to 99% or 98%, and the selectivity of para/ortho was promoted from 1:1 to 1.9:1 or 2.2:1, respectively. A mechanism of anisole benzylation over MoCl5 was proposed, which was different from the traditional Friedel-Crafts alkylation mechanism. Energy & fuels 23 ARTICULO Guo, Qiaoxia 40819 Li, Lianshan 40820 Chen, Liwei 40821 169537 169537 0 0 0 0 237356 BAAB BAAB 2026-03-05 200044339 0 200044339 2026-03-05 15:11:45 2026-03-05 ARTICULO