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Investigation on agglomeration-fragmentation processes in colloidal asphaltene suspensions

By: Publication details: ene. 2009Description: 7 p. ; 967-974 In: Energy & fuels 23Summary: Transcripción del resúmen publicado por el autor: In situ image analyzing measurements are applied in determining the evolution of crude oil asphaltene aggregate size distribution in toluene solutions. The experimental data are compared to the predictions of a population balance model. The effect of different asphaltenes nature on the fractal-like aggregate size is investigated as a function of shear rate and toluene to n-heptane volume ratio. Good agreement is found for the average size evolution of asphaltene aggregate size distribution, assuming a fractal approach for model discretization. Initially, the average-number asphaltene aggregate size increases with time and then beyond a maximum value decreases to an almost constant steady-state size. The aggregates fractal dimension value can strongly affect the evolution kinetics of aggregation.
Item type: Artículo de Revista
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Biblioteca Alejandro Angel Bulgheroni Not for loan 200045051

Transcripción del resúmen publicado por el autor: In situ image analyzing measurements are applied in determining the evolution of crude oil asphaltene aggregate size distribution in toluene solutions. The experimental data are compared to the predictions of a population balance model. The effect of different asphaltenes nature on the fractal-like aggregate size is investigated as a function of shear rate and toluene to n-heptane volume ratio. Good agreement is found for the average size evolution of asphaltene aggregate size distribution, assuming a fractal approach for model discretization. Initially, the average-number asphaltene aggregate size increases with time and then beyond a maximum value decreases to an almost constant steady-state size. The aggregates fractal dimension value can strongly affect the evolution kinetics of aggregation.



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