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Combustion of methane in lean mixtures over bulk transition-metal oxides Evaluation of the activity and self-deactivation

By: Publication details: ene. 2009Description: 7 p. ; 86-93 In: Energy & fuels 23Summary: Transcripción del resúmen publicado por el autor: Different bulk transition-metal oxides (NiO, CuO, Mn2O3, Cr2O3, and Co3O4) were prepared, by precipitation from nitrate precursors, and tested for the combustion of methane-air lean mixtures (1000-5000 ppmv of CH4). Catalyst performances were compared in terms of both intrinsic activity and resistance to self-deactivation. Methane combustion experiments were carried out at ambient pressure and a space velocity of 62 h-1 [weight hourly space velocity (WHSV)]. The activity of the studied catalysts (determined by the recording of light-off curves in the interval of 250-600 °C) decreases in the order: Co3O4 > Mn2O2 > Cr2O3 > CuO > NiO. However, deactivation studies, carried out both at constant temperature (620 °C) and in hysteresis experiments, reveal that Mn2O3 is the most stable catalyst.
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Transcripción del resúmen publicado por el autor: Different bulk transition-metal oxides (NiO, CuO, Mn2O3, Cr2O3, and Co3O4) were prepared, by precipitation from nitrate precursors, and tested for the combustion of methane-air lean mixtures (1000-5000 ppmv of CH4). Catalyst performances were compared in terms of both intrinsic activity and resistance to self-deactivation. Methane combustion experiments were carried out at ambient pressure and a space velocity of 62 h-1 [weight hourly space velocity (WHSV)]. The activity of the studied catalysts (determined by the recording of light-off curves in the interval of 250-600 °C) decreases in the order: Co3O4 > Mn2O2 > Cr2O3 > CuO > NiO. However, deactivation studies, carried out both at constant temperature (620 °C) and in hysteresis experiments, reveal that Mn2O3 is the most stable catalyst.



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