Simultaneous Production of CH4 and H2 from Photocatalytic Reforming of Glucose Aqueous Solution on Sulfated Pd-TiO2 Catalysts (Record no. 189431)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02592nab a2200277 4500 |
| 008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL | |
| Campo de control de longitud fija | 260224s2015 xxu ing |
| 041 ## - IDIOMA | |
| Idioma | Inglés |
| 245 00 - TITULO | |
| Título | Simultaneous Production of CH4 and H2 from Photocatalytic Reforming of Glucose Aqueous Solution on Sulfated Pd-TiO2 Catalysts |
| 260 ## - PUBLICACION, DISTRIBUCION, ETC | |
| Lugar de publicación, distribución, etc. | |
| Nombre de publicador, distribuidor, etc. | |
| Fecha de publicación, distribución, etc. | sept./oct. 2015 |
| 270 ## - FECHA DE CARGA | |
| Fecha de carga | 18/01/2016 ; 18/01/2016 |
| 300 ## - DESCRIPCION FISICA | |
| Otra extensión | 11 p. ; 891-902 |
| 520 ## - RESUMEN, ETC | |
| Resumen | Transcripción del resumen del autor: In this work, the simultaneous production of CH4 and H2 from photocatalytic reforming of glucose aqueous solution on Pd-TiO2 catalysts under UV light irradiation by Light-Emitting Diodes (LED) was investigated. The Pd-TiO2 catalysts were prepared by the photodeposition method. The Pd content was in the range 0.5-2 wt% and a photodeposition time in the range 15-120 min was used. Pd-TiO2 powders were extensively characterized by X-Ray Diffraction (XRD), SBET, X-Ray Fluorescence spectrometry (XRF), UV-Vis Diffuse Reflectance Spectra (UV-Vis DRS), TEM and X-Ray Photoelectron spectroscopy (XPS). It was found that the lower Pd loading (0.5 wt%) and 120 min of photodeposition time allowed us to obtain homogeneously distributed metal nanoparticles of small size; it was also observed that the increase in the metal loading and deposition time led to increasing the Pd0 species effectively deposited on the sulfated TiO2 surface. Particle size and the oxidation state of the palladium were the main factors influencing the photocatalytic activity and selectivity. The presence of palladium on the sulfated titania surface enhanced the H2 and CH4 production. In fact, on the catalyst with 0.5 wt% Pd loading and 120 min of photodeposition time, H2 production of about 26 µmol was obtained after 3 h of irradiation time, higher than that obtained with titania without Pd (about 8.5 µmol). The same result was obtained for the methane production. The initial pH of the solution strongly affected the selectivity of the system. In more acidic conditions, the production of H2 was enhanced, while the CH4 formation was higher under alkaline conditions. |
| 581 ## - ESTADO DE COLECCIÓN | |
| Estado de colección | 5 |
| 773 0# - CORRECCIÓN | |
| Título | Oil and Gas Science and Technology |
| Partes relacionadas | 70 |
| 942 ## - DESC. DE MATERIAL | |
| Tipo de item KOHA | Artículo de Revista |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Vaiano, Vincenzo |
| 9 (RLIN) | 55101 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Lervolino, Giuseppina |
| 9 (RLIN) | 55102 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Sarno, Giuseppe |
| 9 (RLIN) | 55103 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Sannino, Diana |
| 9 (RLIN) | 55104 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Rizzo, Luigi |
| 9 (RLIN) | 55105 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Murcia Mesa, Julie J. |
| 9 (RLIN) | 55106 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Hidalgo, Maria C. |
| 9 (RLIN) | 55107 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Navío, Jose A. |
| 9 (RLIN) | 55108 |
| Biblioteca propietaria | Biblioteca actual | Fecha de adquisición | Inventario | Total de préstamos | Inventario | Fecha de carga | Tipo de item KOHA |
|---|---|---|---|---|---|---|---|
| Biblioteca Alejandro Angel Bulgheroni | Biblioteca Alejandro Angel Bulgheroni | 06/03/2026 | 200061667 | 200061667 | 06/03/2026 | Artículo de Revista |
