Impact of multiphase behavior on coke deposition in a commercial hydrotreating catalyst under sedimentation conditions (Record no. 178026)

MARC details
000 -LEADER
fixed length control field 01973nab a2200229 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s xxu
245 00 - TITULO
Título Impact of multiphase behavior on coke deposition in a commercial hydrotreating catalyst under sedimentation conditions
270 ## - FECHA DE CARGA
Fecha de carga 04/12/2008 ; 06/09/2005
300 ## - DESCRIPCION FISICA
Otra extensión 7 p.
520 ## - RESUMEN, ETC
Resumen TRANSCRIPCIÓN DEL RESUMEN PUBLICADO POR EL AUTOR: Coke deposition in heavy oil catalytic hydroprocessing remains a serious problem. The influence of multiphase behavior on coke deposition is an important but unresolved question in this literature. A model mixture comprising Athabasca vacuum bottoms (ABVB) + decane + hydrogen which is shown to exhibit low-density liquid + vapor, high-density liquid + vapor, as well as low-density liquid + high-density liquid + vapor, phase behavior at typical hydroprocessing conditions and a commercial heavy oil hydrotreating catalyst (NiMo/ -Al2O3) were employed in this investigation. The influence of multiphase behavior on coke deposition was explored under catalyst coking conditions (380 °C and 2 h). The liquid-liquid-vapor region extends from ~20% ABVB to ~50% ABVB. Coke deposition in the high-density liquid phase was found to be greater than in the low-density liquid phase, at fixed global composition. Conventional kinetics models which do not include the impact of such phase behavior effects cannot account for local maxima in the coke deposition versus coke precursor concentration profiles that result when complex phase behavior is encountered.
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas Vol. 19, no. 4 (jul.agos. 2005) ; p. 1405-1411
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Zhang, Xiaohui
9 (RLIN) 47287
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Chodakowski, Martin
9 (RLIN) 47288
650 #0 - MATERIA
Término tópico Deposición de sólidos
9 (RLIN) 47284
650 #0 - MATERIA
Término tópico Catálisis
9 (RLIN) 2782
650 #0 - MATERIA
Término tópico Bitúmenes
9 (RLIN) 1580
650 #0 - MATERIA
Término tópico Petróleos pesados
9 (RLIN) 22736
700 1# - OTRA AUTORIDAD PERSONAL
Nombre Chodakowski, Martin
9 (RLIN) 47288
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200037547   200037547 05/03/2026 Artículo de Revista


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