Catalytic pyrolysis of low-density polyethylene over alumina-supported noble metal catalysts (Record no. 172054)

MARC details
000 -LEADER
fixed length control field 01983nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2010 xxu
245 00 - TITULO
Título Catalytic pyrolysis of low-density polyethylene over alumina-supported noble metal catalysts
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. jul./ago. 2010
270 ## - FECHA DE CARGA
Fecha de carga 23/11/2010 ; 23/11/2010
300 ## - DESCRIPCION FISICA
Otra extensión 10 p. ; 4231–4240
520 ## - RESUMEN, ETC
Resumen Transcripción del resumen del autor. The effects of Pt/Al2O3 and Rh/Al2O3 catalysts on the pyrolysis of low-density polyethylene (LDPE) at a temperature of 425 °C and residence time of 1 h was investigated in a batch stainless steel autoclave reactor. Preliminary observations showed that neither catalyst lowered the degradation temperature of LDPE. Generally, the presence of either catalyst influenced the secondary reactions and improved oil component distribution. Compared to the results from the noncatalytic pyrolysis of LDPE under similar conditions, the catalysts appeared to have caused a slight decrease in the proportion of oil product in favor of coke formation, which increased with increasing catalyst loading. The presence of both catalysts altered the composition of gas products, for instance, both catalysts increased the saturated aliphatic gases to up to 90 wt % of total gas product while alkene gases reduced. It appeared that the catalytic activity of the alumina support toward dehydrogenation and aromatization was predominant. The condensation of the aromatic compounds on the catalyst surface led to coke formation. Deactivation of the catalyst occurred after first use due to carbon deposition. Reactivation of the aged catalyst restored most of their physical properties with differences in their catalytic activities compared to fresh catalysts.
581 ## - ESTADO DE COLECCIÓN
Estado de colección 4
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 24
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Insura, Nagi
9 (RLIN) 43802
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Onwudili, Jude A.
9 (RLIN) 43803
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Williams, Paul T.
9 (RLIN) 43730
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200050024   200050024 05/03/2026 Artículo de Revista


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