Comparative investigation on chemical looping combustion of coal-derived synthesis gas containing H2S over supported NiO oxygen carriers (Record no. 172051)

MARC details
000 -LEADER
fixed length control field 02019nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2010 xxu
245 00 - TITULO
Título Comparative investigation on chemical looping combustion of coal-derived synthesis gas containing H2S over supported NiO oxygen carriers
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. jul./ago. 2010
270 ## - FECHA DE CARGA
Fecha de carga 23/11/2010 ; 23/11/2010
300 ## - DESCRIPCION FISICA
Otra extensión 9 p. ; 4206–4214
520 ## - RESUMEN, ETC
Resumen Transcripción del resumen del autor. Chemical looping combustion (CLC) of simulated coal-derived synthesis gas was conducted with NiO oxygen carriers supported on SiO2, ZrO2, TiO2, and sepiolite. The effect of H2S on the performance of these samples for the CLC process was also evaluated. Five-cycle thermogravimetric analysis (TGA) tests at 800 °C indicated that all oxygen carriers had a stable performance at 800 °C, except NiO/SiO2. Full reduction/oxidation reactions of the oxygen carrier were obtained during the five-cycle test. It was found that support had a significant effect on reaction performance of NiO both in reduction and oxidation rates. The reduction reaction was significantly faster than the oxidation reaction for all oxygen carriers, while the oxidation reaction is fairly slow due to oxygen diffusion on NiO layers. The reaction profile was greatly affected by the presence of H2S, but there was no effect on the capacity due to the presence of H2S in synthesis gas. The presence of H2S decreased reduction reaction rates significantly, but oxidation rates of reduced samples increased. X-ray diffraction (XRD) data of the oxidized samples after a five-cycle test showed stable crystalline phases without any formation of sulfides or sulfites/sulfates. Increase in reaction temperature to 900 °C had a positive effect on the performance.
581 ## - ESTADO DE COLECCIÓN
Estado de colección 4
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 24
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Ksepko, Ewelina
9 (RLIN) 43797
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Siriwardane, Ranjani V.
9 (RLIN) 36889
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Tian, Hanjing
9 (RLIN) 42744
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200050021   200050021 05/03/2026 Artículo de Revista


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