Kinetics and product distributions for thermal cracking of a kerosene-based aviation fuel (Record no. 171077)

MARC details
000 -LEADER
fixed length control field 01988nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título Kinetics and product distributions for thermal cracking of a kerosene-based aviation fuel
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. jul./ago. 2009
270 ## - FECHA DE CARGA
Fecha de carga 15/06/2010 ; 15/06/2010
300 ## - DESCRIPCION FISICA
Otra extensión 4 p. ; 4021-4024
520 ## - RESUMEN, ETC
Resumen Transcripción del resumen del autor. Thermal cracking reactions of a kerosene-based aviation fuel were carried out in a constant-volume reactor, and the kinetics were investigated at different temperatures from 663 to 703 K. The gaseous and liquid products collected from the efflux cooled to room temperature at atmospheric pressure were determined by gas chromatography and gas chromatography-mass spectrometry. The major hydrocarbon components in the gaseous phase were methane, ethane, ethene, propane, and propene; methane had the highest content among them. In the liquid effluence, the contents of components with carbon atom number higher than C11 decreased while those with lower carbon atom number clearly increased with the temperature or reaction time increasing. The gas yield ratios increased with the reaction temperature or time increasing. The thermal cracking kinetic process was correlated well by the pseudo first-order kinetic equation. The correlation followed that the rate constants were in the range 0.163 × 10-2 h-1 at 663 K to 2.809 × 10-2 h-1 at 703 K. The Arrhenius parameters were then derived with the values of the apparent activation energy Ea of 280 ± 6.5 kJ mol-1 and the logarithm of the pre-exponential factor, log A = 19.3 ± 0.5. The values were in reasonable agreements with those for the first-order decomposition of the chain alkanes such as n-dodecane.
581 ## - ESTADO DE COLECCIÓN
Estado de colección 4
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Fang, Wenjun
9 (RLIN) 41594
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Xie, Wenjie
9 (RLIN) 41595
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Xing, Yan
9 (RLIN) 38233
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200045935   200045935 05/03/2026 Artículo de Revista


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