Composition-explicit distillation curves for mixtures of diesel fuel with dimethyl carbonate and diethyl carbonate (Record no. 171073)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02532nab a2200205 4500 |
| 008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL | |
| Campo de control de longitud fija | 260224s2009 xxu |
| 245 00 - TITULO | |
| Título | Composition-explicit distillation curves for mixtures of diesel fuel with dimethyl carbonate and diethyl carbonate |
| 260 ## - PUBLICACION, DISTRIBUCION, ETC | |
| Lugar de publicación, distribución, etc. | |
| Nombre de publicador, distribuidor, etc. | |
| Fecha de publicación, distribución, etc. | jul./ago. 2009 |
| 270 ## - FECHA DE CARGA | |
| Fecha de carga | 15/06/2010 ; 15/06/2010 |
| 300 ## - DESCRIPCION FISICA | |
| Otra extensión | 9 p. ; 3989-3997 |
| 520 ## - RESUMEN, ETC | |
| Resumen | Transcripción del resumen del autor. We have recently introduced several important improvements in the measurement of distillation curves of complex fluids. The modifications to the classical measurement provide for (1) a composition-explicit data channel for each distillate fraction (for qualitative, quantitative, and trace analysis); (2) temperature measurements that are true thermodynamic state points that can be modeled with an equation of state; (3) temperature, volume, and pressure measurements of low uncertainty suitable for equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; and (6) a corrosivity assessment of each distillate fraction. We have applied the new method to the measurement of rocket propellant, gasolines, jet fuels, and hydrocarbon crude oils. In this paper, we present the application of the technique to representative batches of ultra low sulfur diesel fuel (ULSD) and mixtures of this diesel fuel with two of the more promising oxygenating agents; namely, dimethyl carbonate and diethyl carbonate. The addition of oxygenates, although more familiar in gasoline fuel systems, is also of great interest in the diesel fuel community, since it provides an opportunity to decrease particulate emissions. The potential of designing new fuel mixtures critically depends on knowledge of the thermophysical properties of the fluids. The volatility, as provided by the distillation curve method we apply, is part of that knowledge base. We present herein the distillation curves as a function of additive starting concentration and the concurrent analytical information. We noted that even after the oxygenates have distilled out of the mixtures, there is a persistent depression in the temperature. An explanation in terms of the Helmholtz free energy equation of state model is advanced. |
| 581 ## - ESTADO DE COLECCIÓN | |
| Estado de colección | 4 |
| 773 0# - CORRECCIÓN | |
| Título | Energy & fuels |
| Partes relacionadas | 23 |
| 942 ## - DESC. DE MATERIAL | |
| Tipo de item KOHA | Artículo de Revista |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Bruno, Thomas J. |
| 9 (RLIN) | 41674 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Wolk, Arron |
| 9 (RLIN) | 41675 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Naydich, Alexander |
| 9 (RLIN) | 41676 |
| Biblioteca propietaria | Biblioteca actual | Fecha de adquisición | Inventario | Total de préstamos | Inventario | Fecha de carga | Tipo de item KOHA |
|---|---|---|---|---|---|---|---|
| Biblioteca Alejandro Angel Bulgheroni | Biblioteca Alejandro Angel Bulgheroni | 05/03/2026 | 200045931 | 200045931 | 05/03/2026 | Artículo de Revista |
