Role of surface oxygen-containing functional groups in liquid-phase adsorption of nitrogen compounds on carbon-based adsorbents (Record no. 171067)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 02510nab a2200205 4500 |
| 008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL | |
| Campo de control de longitud fija | 260224s2009 xxu |
| 245 00 - TITULO | |
| Título | Role of surface oxygen-containing functional groups in liquid-phase adsorption of nitrogen compounds on carbon-based adsorbents |
| 260 ## - PUBLICACION, DISTRIBUCION, ETC | |
| Lugar de publicación, distribución, etc. | |
| Nombre de publicador, distribuidor, etc. | |
| Fecha de publicación, distribución, etc. | jul./ago. 2009 |
| 270 ## - FECHA DE CARGA | |
| Fecha de carga | 15/06/2010 ; 15/06/2010 |
| 300 ## - DESCRIPCION FISICA | |
| Otra extensión | 8 p. ; 3940-3947 |
| 520 ## - RESUMEN, ETC | |
| Resumen | Transcripción del resumen del autor. The carbon-based adsorbents are promising for adsorptive denitrogenation (ADN) of liquid hydrocarbon streams. The objective of the present study is to develop a fundamental understanding of the role of surface oxygen-containing functional groups on carbon-based adsorbents in adsorption of nitrogen compounds that are known to be present in liquid fuels. The adsorption properties of four representative activated carbons were evaluated in a batch adsorption system for removing quinoline and indole respectively from decane. The adsorption was found to obey the Langmuir adsorption isotherm. The adsorption isotherms were obtained and the adsorption parameters (the maximum capacity and adsorption constant) were estimated. The surface chemical properties of the adsorbents were characterized by temperature-programmed desorption (TPD) technique with a mass spectrometer to identify and quantify the type and concentration of the oxygen-containing functional groups on the basis of the CO2- and CO-evolution profiles. It was found that both the type and the concentration of surface oxygen-containing functional groups play an important role in determining the ADN performance. Higher concentration of the oxygen-containing functional groups on the adsorbents resulted in higher adsorption capacity for the nitrogen compounds. A fundamental insight was gained on the contributions of different oxygen functional groups by analyzing the changes in the monolayer maximum adsorption capacity qm and the adsorption constant K for nitrogen compounds on different carbon adsorbents. The acidic functional groups, such as carboxyl and carboxylic anhydride groups, appear to contribute more for adsorption of quinoline, whereas the basic oxygen-containing groups such as carbonyl and quinone groups may have more contribution to adsorption of indole. |
| 581 ## - ESTADO DE COLECCIÓN | |
| Estado de colección | 4 |
| 773 0# - CORRECCIÓN | |
| Título | Energy & fuels |
| Partes relacionadas | 23 |
| 942 ## - DESC. DE MATERIAL | |
| Tipo de item KOHA | Artículo de Revista |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Almarri, Masoud |
| 9 (RLIN) | 42757 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Ma, Xiaoliang |
| 9 (RLIN) | 36289 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Song, Chunshan |
| 9 (RLIN) | 35995 |
| Biblioteca propietaria | Biblioteca actual | Fecha de adquisición | Inventario | Total de préstamos | Inventario | Fecha de carga | Tipo de item KOHA |
|---|---|---|---|---|---|---|---|
| Biblioteca Alejandro Angel Bulgheroni | Biblioteca Alejandro Angel Bulgheroni | 05/03/2026 | 200045925 | 200045925 | 05/03/2026 | Artículo de Revista |
