Hydrodesulfurization of fluidized catalytic cracking diesel oil over NiW/AMB catalysts containing H-type ß-zeolite in situ synthesized from Kaolin material (Record no. 171056)

MARC details
000 -LEADER
fixed length control field 02240nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título Hydrodesulfurization of fluidized catalytic cracking diesel oil over NiW/AMB catalysts containing H-type ß-zeolite in situ synthesized from Kaolin material
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. jul./ago. 2009
270 ## - FECHA DE CARGA
Fecha de carga 15/06/2010 ; 15/06/2010
300 ## - DESCRIPCION FISICA
Otra extensión 7 p. ; 3846-3852
520 ## - RESUMEN, ETC
Resumen Transcripción del resumen del autor. A series of hydrodesulfurization (HDS) catalysts of Ni-W supported on -Al2O3-MB (denoted as AMB) composites with various amounts of H-type ß zeolite (denoted as MB) synthesized from kaolin were prepared. The samples were characterized by means of N2 physisorption, XRD, SEM, TPR, HRTEM, XPS, and FT-IR spectroscopy of pyridine adsorption. The characterization results showed that, compared with NiW/Al2O3, the addition of MB reduced the interaction between W and the support. The addition of MB made the WS2 slabs grow larger and the stacking degree become higher. The addition of MB also enhanced the overall acidity of AMB supports and led to an increase in the ratio of Brnsted acid of the NiW catalysts. W exhibited higher sulfidation extent in MB-containing NiW/AMB3 catalyst than that in NiW/Al2O3. The fluidized catalytic cracking (FCC) diesel HDS activity changed with the addition of varying amounts of MB on NiW/AMBi catalysts. The optimal MB content was 32 wt % in composite AMB support. A higher deep HDS efficiency was achieved on NiW/AMB3 than that of traditional NiW/Al2O3. Higher HDS activity of NiW/AMB3 was attributed to the appropriate ratio of Brnsted acid to Lewis acid and/or the enhanced hydrogenation activity. For NiW/AMB3 catalyst, the effect of operation conditions on the degree of HDS of FCC diesel was investigated. The ultradeep desulfurization of FCC diesel oil, in which the sulfur content is below 10 ppm, could be obtained under the optimal operation conditions: T = 360 °C, P = 5 MPa, LHSV = 1 h-1, and H2/oil = 600.
581 ## - ESTADO DE COLECCIÓN
Estado de colección 4
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Wan, Guofu
9 (RLIN) 40833
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Duan, Aijun
9 (RLIN) 40834
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Zhang, Ying
9 (RLIN) 42733
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200045914   200045914 05/03/2026 Artículo de Revista


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