Removal of dibenzothiophenes from fuels by oxy-desulfurization (Record no. 170843)

MARC details
000 -LEADER
fixed length control field 02168nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título Removal of dibenzothiophenes from fuels by oxy-desulfurization
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. nov./dic. 2009
270 ## - FECHA DE CARGA
Fecha de carga 09/06/2010 ; 09/06/2010
300 ## - DESCRIPCION FISICA
Otra extensión 9 p. ; 5986-5994
520 ## - RESUMEN, ETC
Resumen Transcripción del resumen del autor. Removal of sulfur species from fuels is an increasingly critical environmental issue. Hydrodesulfurization (HDS) removes sulfur compounds, such as mercaptans and sulfides, from hydrocarbons; however, some sulfur-containing compounds are very difficult to remove and need deep desulfurization processes. In this study, another approach is explored, where dibenzothiophene can be removed from the HDS products by a liquid-phase process. Four different sulfur removal approaches are tested: oxidation, extraction, consecutive oxidation and extraction, and simultaneous oxidation and extraction. A detailed parametric experimental study was performed to select the best technique for the specified purpose of this investigation. n-Octane doped with dibenzothiophenes is used as a model fuel, which is extracted by polar solvents [N-methyl-2-pyrolidone (NMP), dimethyl formamide (DMF), and acetonitrile (ACN)]. These solvents are found to have a moderate capability of removing sulfur species. Applying oxidation in the liquid phase resulted in partial removal of the sulfur content, but most of the sulfur components are not removed from the fuel phase. However, applying both oxidation and extraction steps (either consecutively or simultaneously) resulted in dissolution of sulfur production in the solvent phase. NMP was found to be the best solvent (among the tested ones in this investigation) for the removal of oxidized sulfur species. This is related to the high capability of NMP (polar solvent) for the removal of oxidized (polar) sulfur species (sulfones).
581 ## - ESTADO DE COLECCIÓN
Estado de colección 6
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Ali, Sami H.
9 (RLIN) 42394
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Hamad, Dina M.
9 (RLIN) 42395
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Albusairi, Bader H.
9 (RLIN) 42396
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200045697   200045697 05/03/2026 Artículo de Revista


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