Absorption spectrophotometric study of molecular complexation of asphaltene with bromanil (Record no. 169596)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 01737nab a2200205 4500 |
| 008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL | |
| Campo de control de longitud fija | 260224s2009 xxu |
| 245 00 - TITULO | |
| Título | Absorption spectrophotometric study of molecular complexation of asphaltene with bromanil |
| 260 ## - PUBLICACION, DISTRIBUCION, ETC | |
| Lugar de publicación, distribución, etc. | |
| Nombre de publicador, distribuidor, etc. | |
| Fecha de publicación, distribución, etc. | ene. 2009 |
| 270 ## - FECHA DE CARGA | |
| Fecha de carga | 15/05/2009 ; 17/04/2009 |
| 300 ## - DESCRIPCION FISICA | |
| Otra extensión | 4 p. ; 392-396 |
| 520 ## - RESUMEN, ETC | |
| Resumen | Transcripción del resúmen publicado por el autor: It has been shown by UV-vis spectrophotometric method that p-bromanil forms inclusion complex of 1:2 stoichiometry with coal-derived asphaltenes. The absorption peak for the complex has been detected by difference spectral method and has been compared with those for complexes involving chloranils. The wavelengths of the maximum absorption are in the expected order of electron affinities of the chloranils and bromanil. The formation constants (K) have been determined using the Benesi-Hildebrand equation. The magnitudes of K are large compared to those of weak charge transfer complexes (for which K ˜ 101 to 103 dm3 mol-1) but are comparable to those of some recently reported supramolecular or inclusion complexes. The study reveals the presence of p-donor (i.e., aromatic) type of groups in asphaltene molecule. It also supports the view that bromanil molecules get included into structures provided by asphaltene molecules. Thermodynamic parameters H0 sand S0 for the complexation process have also been determined. |
| 773 0# - CORRECCIÓN | |
| Título | Energy & fuels |
| Partes relacionadas | 23 |
| 942 ## - DESC. DE MATERIAL | |
| Tipo de item KOHA | Artículo de Revista |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Ghosh, Ashish Kumar |
| 9 (RLIN) | 40938 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Mukherjee, Asok Kumar |
| 9 (RLIN) | 40939 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Bagchi, Sanjib |
| 9 (RLIN) | 40940 |
| 856 ## - LINK | |
| Link | <a href="http://pubs.acs.org/doi/full/10.1021/ef800746z">http://pubs.acs.org/doi/full/10.1021/ef800746z</a> |
| Biblioteca propietaria | Biblioteca actual | Fecha de adquisición | Inventario | Total de préstamos | Inventario | Fecha de carga | Tipo de item KOHA |
|---|---|---|---|---|---|---|---|
| Biblioteca virtual | Biblioteca virtual | 05/03/2026 | 200044399 | 200044399 | 05/03/2026 | Artículo de Revista |
