Solubility parameters of bitumen-derived narrow vacuum resid fractions (Record no. 169595)

MARC details
000 -LEADER
fixed length control field 02373nab a2200205 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título Solubility parameters of bitumen-derived narrow vacuum resid fractions
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. ene. 2009
270 ## - FECHA DE CARGA
Fecha de carga 15/05/2009 ; 17/04/2009
300 ## - DESCRIPCION FISICA
Otra extensión 5 p. ; 386-391
520 ## - RESUMEN, ETC
Resumen Transcripción del resúmen publicado por el autor: Narrow fractions of Athabasca vacuum topped bitumen (VTB) were prepared by supercritical fluid extraction and fractionation (SFEF) and characterized. Phase equilibria of various narrow fractions in the propane system were determined using a high-pressure PVT unit, operating at 30-50 °C, 4-6 MPa, and solvent/oil (S/O) ratio of 1.5 to 5 (wt/wt). Solubility parameters were determined using the activity coefficient equation from Scathard-Hildebrand’s regular solution theory. The value of the solubility parameter of the VTB fraction was obtained by extrapolation of the Gaussian function at the S/O ratio approaching zero. It was found that the solubility parameter of the VTB fraction was not constant, varying from 14 to 16 MPa1/2. The solubility parameter exhibited a Gaussian distribution as a function of the S/O ratio, with a maximum at the S/O ratio of 3.25, and a parabolic function of pressure, with a maximum at 5 MPa. It decreased with temperature. As the VTB fraction becomes heavier, the solubility parameter of the VTB fraction and the maximum value of the solubility parameter increased. The solubility parameter of the VTB end-cut (primarily C5-insoluble asphaltenes) was obtained using a modified titration method by varying the composition of a pentane/toluene blend solvent. The correlation of the solubility parameter of the VTB fraction was derived as a function of various key feedstock properties. The measured solubility parameters of narrow VTB fractions were compared to predictions from five published models. The results showed that the published models overestimate solubility parameters of the VTB fractions. In some cases, the trend of predictions was inconsistent.
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Wang, Xingyi
9 (RLIN) 40937
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Xu, Zhiming
9 (RLIN) 26204
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Zhao, Suoqi
9 (RLIN) 26203
856 ## - LINK
Link <a href="http://pubs.acs.org/doi/full/10.1021/ef800697f">http://pubs.acs.org/doi/full/10.1021/ef800697f</a>
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca virtual Biblioteca virtual 05/03/2026 200044398   200044398 05/03/2026 Artículo de Revista


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