Mercury oxidation over a vanadia-based selective catalytic reduction catalyst (Record no. 169564)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 01821nab a2200205 4500 |
| 008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL | |
| Campo de control de longitud fija | 260224s2009 xxu |
| 245 00 - TITULO | |
| Título | Mercury oxidation over a vanadia-based selective catalytic reduction catalyst |
| 260 ## - PUBLICACION, DISTRIBUCION, ETC | |
| Lugar de publicación, distribución, etc. | |
| Nombre de publicador, distribuidor, etc. | |
| Fecha de publicación, distribución, etc. | ene. 2009 |
| 270 ## - FECHA DE CARGA | |
| Fecha de carga | 15/05/2009 ; 15/04/2009 |
| 300 ## - DESCRIPCION FISICA | |
| Otra extensión | 6 p. ; 253-259 |
| 520 ## - RESUMEN, ETC | |
| Resumen | Transcripción del resúmen publicado por el autor: The process of the reaction among elemental mercury (Hg0) and reactive flue gas components across the selective catalytic reduction (SCR) catalyst was studied in a laboratory-scale reactor. Prepared vanadia-based SCR catalysts were characterized and analyzed to understand the potential reaction pathways. Mercury oxidation was observed when pro-exposure of the SCR catalyst to HCl, followed by passing through Hg0/N2 in the absence of gas-phase HCl. At testing conditions, Hg0 was found to desorb from the catalyst surface by adding HCl to the gas steam, which implies that HCl adsorption onto the SCR catalyst is strong relative to the mercury. Surface analysis verified the absorption of HCl onto the SCR catalysts, and the potential reaction pathways were proposed. Indeed, the monomeric vanadyl sites on the catalyst surface were found to be responsible for the adsorption of both Hg0 and HCl, which means they are active for mercury oxidation. Furthermore, the detailed Langmuir-Hinshelwood mechanism was proposed to explain the mercury oxidation on the SCR catalyst, where reactive Cl generated from adsorbed HCl reacts with adjacent Hg0. |
| 773 0# - CORRECCIÓN | |
| Título | Energy & fuels |
| Partes relacionadas | 23 |
| 942 ## - DESC. DE MATERIAL | |
| Tipo de item KOHA | Artículo de Revista |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | He, Sheng |
| 9 (RLIN) | 40887 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Zhou, Jinsong |
| 9 (RLIN) | 38081 |
| 100 1# - RESPONSABLE PERSONAL | |
| Apellido, Nombre | Zhu, Yanqun |
| 9 (RLIN) | 40888 |
| 856 ## - LINK | |
| Link | <a href="http://pubs.acs.org/doi/full/10.1021/ef800730f">http://pubs.acs.org/doi/full/10.1021/ef800730f</a> |
| Biblioteca propietaria | Biblioteca actual | Fecha de adquisición | Inventario | Total de préstamos | Inventario | Fecha de carga | Tipo de item KOHA |
|---|---|---|---|---|---|---|---|
| Biblioteca virtual | Biblioteca virtual | 05/03/2026 | 200044366 | 200044366 | 05/03/2026 | Artículo de Revista |
