CO2 gasification of biomass chars (Record no. 169545)

MARC details
000 -LEADER
fixed length control field 02122nab a2200193 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título CO2 gasification of biomass chars
Subtítulo A kinetic study
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. ene. 2009
270 ## - FECHA DE CARGA
Fecha de carga 14/04/2009 ; 14/04/2009
300 ## - DESCRIPCION FISICA
Otra extensión 6 p. ; 94-100
520 ## - RESUMEN, ETC
Resumen Transcripción del resúmen publicado por el autor: The CO2 gasification of pine and birch charcoals was studied by thermogravimetric analysis (TGA) at CO2 partial pressures of 51 and 101 kPa. Linear and stepwise heating programs were employed to increase the information content of the experimental data sets. Low sample masses were used because of the high enthalpy change. Seven experiments with different experimental conditions were evaluated simultaneously for each sample. The method of least-squares was employed. Three reactions appeared in the temperature domain evaluated (600-1000 °C). The first and second reactions were due to the devolatilization and did not show a significant dependence upon the CO2 concentration. They were approximated by first-order kinetics. The third reaction corresponded to the gasification. Its modeling was based on an empirical approximation of the change of the reaction surface during the gasification and by a formal reaction order with respect to the CO2 concentration. Very close results were obtained for the two charcoals. The dependence upon the conversion could be well-approximated by power law kinetics. In the next step of the evaluation, the experiments of the two samples (14 experiments combined) were evaluated together, assuming common activation energy values and a common reaction order with respect to the CO2 concentration. This process led to nearly the same fit as the separate evaluation of the two samples. The activation energy of the gasification step was 262 kJ/mol. The reaction order of CO2 was 0.40.
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Khalil, Roger
9 (RLIN) 40839
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Várhegyi, Gábor
9 (RLIN) 35978
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Jäschke, Susanne
9 (RLIN) 40840
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200044347   200044347 05/03/2026 Artículo de Revista


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