Studies of NO-Char reaction kinetics obtained from drop-tube furnace and thermogravimetric experiments (Record no. 169542)

MARC details
000 -LEADER
fixed length control field 02028nab a2200193 4500
008 - CÓDIGOS DE INFORMACIÓN DE LONGITUD FIJA - INFORMACIÓN GENERAL
Campo de control de longitud fija 260224s2009 xxu
245 00 - TITULO
Título Studies of NO-Char reaction kinetics obtained from drop-tube furnace and thermogravimetric experiments
260 ## - PUBLICACION, DISTRIBUCION, ETC
Lugar de publicación, distribución, etc.
Nombre de publicador, distribuidor, etc.
Fecha de publicación, distribución, etc. ene. 2009
270 ## - FECHA DE CARGA
Fecha de carga 14/04/2009 ; 14/04/2009
300 ## - DESCRIPCION FISICA
Otra extensión 6 p. ; 74-80
520 ## - RESUMEN, ETC
Resumen Transcripción del resúmen publicado por el autor: Four coal chars were prepared in a flat flame flow reactor (FFR), which can simulate the temperature and gas composition of a real pulverized coal combustion environment. The pore structure of chars was measured by mercury porosimetry and nitrogen adsorption, and the Hg and Brunauer-Emmett-Teller (BET) surface areas were obtained. The kinetics of NO-char was studied in a drop-tube furnace (DTF) and thermogravimetric analyzer (TGA). In the TGA experiments, the random pore model (RPM) was applied to describe the NO-char reactions and obtain the intrinsic kinetics. By presenting the data of DTF and TGA experiments on the same Arrhenius plot, it can be concluded that TGA is an available tool to study the kinetics of a high-temperature NO-char reaction. With respect to the DTF experiments, in comparison to the BET surface area, the Hg surface area is a better basis for normalizing the reactivity of different coal chars because of less scatter in the measured values, better agreement with TGA experimental data, and more stable values during the process of reaction. Moreover, by comparing the Hg surface area of chars before and after reactions, it is believed that the Hg surface area basis is more appropriate for high-rank coal chars. The determined kinetic rate constants are in good agreement with other data in the literature, and a new rate constant expression is proposed.
773 0# - CORRECCIÓN
Título Energy & fuels
Partes relacionadas 23
942 ## - DESC. DE MATERIAL
Tipo de item KOHA Artículo de Revista
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Sun, Shaozeng
9 (RLIN) 38133
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Zhang, Juwei
9 (RLIN) 40831
100 1# - RESPONSABLE PERSONAL
Apellido, Nombre Hu, Xidong
9 (RLIN) 40832
Holdings
Biblioteca propietaria Biblioteca actual Fecha de adquisición Inventario Total de préstamos Inventario Fecha de carga Tipo de item KOHA
Biblioteca Alejandro Angel Bulgheroni Biblioteca Alejandro Angel Bulgheroni 05/03/2026 200044344   200044344 05/03/2026 Artículo de Revista


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