Dilute iota- and kappa-carrageenan solutions with high viscosities in high
Dilute iota- and kappa-carrageenan solutions with high viscosities in high
- ene. 2011
- 7 p. ; 304-311
Transcripción del resumen del autor: We evaluated the rheological characteristics of - and -Carrageenan in aqueous solutions. Viscosities strongly increased with increasing polymer concentration or salinity. Monovalent Na+ cations were more effective in increasing viscosity than divalent Ca2+ cations. A more complex brine containing Na+, Mg2+ and Ca2+ cations also showed high viscosities at a high salinity. We observed shear thinning behavior for these polysaccharide solutions. We explain these rheological phenomena with molecular processes, specifically the conformation change of the -Carrageenan from random coil to double helix. In the context of enhanced oil recovery, -Carrageenan solutions can reach much higher viscosities at high salinities than standard polyacrylamide solutions. Moreover, Carrageenans are renewable, nontoxic, green substances.
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Transcripción del resumen del autor: We evaluated the rheological characteristics of - and -Carrageenan in aqueous solutions. Viscosities strongly increased with increasing polymer concentration or salinity. Monovalent Na+ cations were more effective in increasing viscosity than divalent Ca2+ cations. A more complex brine containing Na+, Mg2+ and Ca2+ cations also showed high viscosities at a high salinity. We observed shear thinning behavior for these polysaccharide solutions. We explain these rheological phenomena with molecular processes, specifically the conformation change of the -Carrageenan from random coil to double helix. In the context of enhanced oil recovery, -Carrageenan solutions can reach much higher viscosities at high salinities than standard polyacrylamide solutions. Moreover, Carrageenans are renewable, nontoxic, green substances.
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