Decreasing contactor temperature could increase performance
Lunsford, Kevin M. McIntyre, Gavin
Decreasing contactor temperature could increase performance - Texas Bryan Research & Engineering 2001
Artículo publicado en la página web de Bryan Research & Engineering (http://www.bre.com) donde se pueden consultar otros artículos sobre temas relacionados. ; Página web visitada en enero de 2004. ; Navegadores de Internet
Transcripción del resumen presentado por el autor, en inglés: Gas treating process variables such as solvent type and concentration, pressure, and circulation can be manipulated to produce specification quality hydrocarbon products. Interest has increased recently in exploring the effects of inlet gas and solvent temperatures as an aid in meeting these specifications. In general, lower temperatures tend to promote absorption of lower molecular weight components based on vapor-liquid equilibrium. Physical solvents exploit this principle by absorbing acid gases and water at lower temperatures. If the absorption process is reactive and allowed to reach equilibrium, lower temperatures still favor the absorption of low molecular weight components. However, if the reactive absorption is kinetically limited as is the case with CO2 and certain amines, it is impossible to determine how temperature affects the absorption in the absence of additional information. This ambiguity results from the competing phenomena and opposite effect temperature has on reaction rates and solubility. For absorption of H2S and CO2 in alkanolamines or mixtures of amines with physical solvents, H2S absorption reaches equilibrium conditions while CO2 absorption is kinetically limited in some situations. The performance of various amines and physical solvents are compared based on solvent and feed gas temperatures. Understanding the competing phenomena of equilibrium and kinetics may yield situations where this effect can be exploited for more profitable operation.
Tratamiento de gas natural
Procesos químicos
Cinética química
Propiedades de los hidrocarburos
Propiedades del gas natural
Propiedades de los alcoholes
Propiedades termodinámicas
Propiedades termoquímicas
Extracción con solventes
Tratamiento de gas con aminas
Tratamiento de gas con glicoles
Desulfurización
Deshidratación
Extracción de dióxido de carbono
Diagrama de flujos
Decreasing contactor temperature could increase performance - Texas Bryan Research & Engineering 2001
Artículo publicado en la página web de Bryan Research & Engineering (http://www.bre.com) donde se pueden consultar otros artículos sobre temas relacionados. ; Página web visitada en enero de 2004. ; Navegadores de Internet
Transcripción del resumen presentado por el autor, en inglés: Gas treating process variables such as solvent type and concentration, pressure, and circulation can be manipulated to produce specification quality hydrocarbon products. Interest has increased recently in exploring the effects of inlet gas and solvent temperatures as an aid in meeting these specifications. In general, lower temperatures tend to promote absorption of lower molecular weight components based on vapor-liquid equilibrium. Physical solvents exploit this principle by absorbing acid gases and water at lower temperatures. If the absorption process is reactive and allowed to reach equilibrium, lower temperatures still favor the absorption of low molecular weight components. However, if the reactive absorption is kinetically limited as is the case with CO2 and certain amines, it is impossible to determine how temperature affects the absorption in the absence of additional information. This ambiguity results from the competing phenomena and opposite effect temperature has on reaction rates and solubility. For absorption of H2S and CO2 in alkanolamines or mixtures of amines with physical solvents, H2S absorption reaches equilibrium conditions while CO2 absorption is kinetically limited in some situations. The performance of various amines and physical solvents are compared based on solvent and feed gas temperatures. Understanding the competing phenomena of equilibrium and kinetics may yield situations where this effect can be exploited for more profitable operation.
Tratamiento de gas natural
Procesos químicos
Cinética química
Propiedades de los hidrocarburos
Propiedades del gas natural
Propiedades de los alcoholes
Propiedades termodinámicas
Propiedades termoquímicas
Extracción con solventes
Tratamiento de gas con aminas
Tratamiento de gas con glicoles
Desulfurización
Deshidratación
Extracción de dióxido de carbono
Diagrama de flujos



