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Chromium species as captors of sulfur molecules on nickel-based hydrotreating catalysts

By: Publication details: ene. 2009Description: 9 p. ; 101-110 In: Energy & fuels 23Summary: Transcripción del resúmen publicado por el autor: Three nickel-chromium catalysts supported on aluminated mesoporous silica (SBA-15) were prepared with a fixed nickel loading of 15 wt % and differing chromium contents, which ranged between 2.6 and 5.2 wt %. They were tested in the hydrotreating of tetralin in the presence of dibenzothiophene (DBT). Moreover, a monometallic nickel catalyst was also prepared and tested, for comparison. Information regarding the structure of the calcined, reduced, and used catalysts was obtained by several physical-chemical techniques such as X-ray diffraction (XRD), hydrogen temperature-programmed reduction (H2-TPR), temperature-programmed desorption of ammonia (NH3-TPD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and elemental chemical analysis. The presence of small amounts of Cr3+ ions not only modifies the nickel dispersion, leading to the formation of a more active catalyst in the hydrogenation of tetralin, but also has a strong influence on the stability of these catalysts in the presence of 425 ppm DBT in the feed. The Cr3+ ions seem to act as a sulfur trap, thus preventing sulfur poisoning of nickel particles.
Item type: Artículo de Revista
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Biblioteca Alejandro Angel Bulgheroni Not for loan 200044348

Transcripción del resúmen publicado por el autor: Three nickel-chromium catalysts supported on aluminated mesoporous silica (SBA-15) were prepared with a fixed nickel loading of 15 wt % and differing chromium contents, which ranged between 2.6 and 5.2 wt %. They were tested in the hydrotreating of tetralin in the presence of dibenzothiophene (DBT). Moreover, a monometallic nickel catalyst was also prepared and tested, for comparison. Information regarding the structure of the calcined, reduced, and used catalysts was obtained by several physical-chemical techniques such as X-ray diffraction (XRD), hydrogen temperature-programmed reduction (H2-TPR), temperature-programmed desorption of ammonia (NH3-TPD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and elemental chemical analysis. The presence of small amounts of Cr3+ ions not only modifies the nickel dispersion, leading to the formation of a more active catalyst in the hydrogenation of tetralin, but also has a strong influence on the stability of these catalysts in the presence of 425 ppm DBT in the feed. The Cr3+ ions seem to act as a sulfur trap, thus preventing sulfur poisoning of nickel particles.



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